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本帖最后由 lwjxz 于 2018-1-20 15:43 编辑
哈佛大学Myers 编著 Chemistry 215 Handouts (高等有机反应集锦)
资料目录 Contents
1. Reduction 1-17 Lithium-Halogen Exchange
2. Oxidation 18-45 Organolithium Reagents
3. Protective Groups – Silicon-Based Protection of the Hydroxyl Group 46-50
4. Protective Groups – Protection of Hydroxyl Groups, Acetals 51-52
5. Protective Groups – Protection of Hydroxyl Groups, Ethers 53
6. Protective Groups – Protection of 1,2- and 1,3-Diols 54-55
7. Protective Groups – Selective Protection of Carbohydrates 56-60
8. Protective Groups – Protection of Phenols 61
9. Protective Groups – Protection of the Carbonyl Group 62-64
10. Protective Groups – Protection of the Carboxyl Group 65-67
11. Protective Groups – Protection of the Amino Group 68-71
12. Birch Reduction 72-78
13. Asymmetric Alkylation of Enolates 79-85
14. Catalytic Methods for Asymmetric Alkylation 86
15. Asymmetric Allylation Reactions 87-95
16. Magnesium-Halogen Exchange 96-100
17. Organolithium Reagents 101-103
18. Lithium-Halogen Exchange 104-106
19. Directed Ortho Metalation 107-110
20. The Stille Reaction 111-121
21. The Suzuki Reaction 122-131
22. The Heck Reaction 132-139
23. Stereoselective, Directed Aldol Reaction 140-162
24. Horner-Wadsworth-Emmons Olefination 163-171
25. Sharpless Asymmetric Epoxidation Reaction 172-175
26. Sharpless Asymmetric Dihydroxylation Reaction 176-179
27. Jacobsen Asymmetric Epoxidation Reaction 180-181
28. Shi Asymmetric Epoxidation Reaction 182-186
29. Jacobsen Catalytic Asymmetric Epoxide-Opening Reactions 187-189
30. Transformations of 2,3-Epoxy Alcohols 190-192
31. The Noyori Asymmetric Hydrogenation Reaction 193-200
32. Asymmetric Diels–Alder Reactions 201-216
33. The Olefin Metathesis Reaction 217-239
34. Synthesis of Chiral Amines by Asymmetric Additions to tert-Butylsulfinimines (Ellman Auxiliary) 241-246
35 The Nozaki–Hiyama–Kishi Reaction, Asymmetric Additions to Carbonyl Compounds 247-252
36. Organozinc Reagents: Asymmetric Additions to Carbonyl Compounds 253-264
37 Stereoselective Olefination Reactions:265-287
38. Hydrozirconation and Carbozirconation 288-298
39. C–N Bond-Forming Reactions 299-314
40. C–O Bond-Forming Reactions: 315-322
41. Metal-Catalyzed C!O Bond-Forming Reactions 323-333
42. Anionic Cyclization Reactions 333-348
43. Cyclopropanation 349-359
44. Cyclobutane Synthesis 360-369
45. 5-Membered Ring Synthesis by Radical Cyclization 370-380
46. Methods for Ring Contraction 381-391
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